| 6‑Nov‑2023 | Metz | Hard | SF | 344 | 63 | Alexander Shevchenko [KAZ] d. (WC)Herbert | 6-4 6-4 | (ch) | 0.73 | 16.1% | 4.8% | 72.6% | 68.9% | 29.4% | 4/7 | 1:17 |
| 8‑Mar‑2021 | Marseille | Hard | SF | 93 | 31 | Herbert d. (4)Ugo Humbert [FRA] | 6-3 6-2 | | 3.07 | 21.4% | 2.4% | 69.0% | 86.2% | 84.6% | 0/0 | 1:05 |
| 17‑Jun‑2019 | Halle | Grass | SF | 43 | 3 | (1)Roger Federer [SUI] d. Herbert | 6-3 6-3 | | 0.30 | 16.4% | 4.9% | 63.9% | 69.2% | 40.9% | 5/8 | 1:02 |
| 22‑Apr‑2019 | Budapest | Clay | SF | 49 | 105 | (Q)Filip Krajinovic [SRB] d. Herbert | 6-2 6-2 | | 0.32 | 4.1% | 4.1% | 69.4% | 55.9% | 40.0% | 4/8 | 0:59 |
| 4‑Feb‑2019 | Montpellier | Hard | SF | 44 | 79 | (7)Herbert d. Tomas Berdych [CZE] | 6-2 7-5 | | 1.41 | 8.1% | 4.8% | 51.6% | 84.4% | 60.0% | 3/3 | 1:33 |
| 24‑Sep‑2018 | Shenzhen | Hard | SF | 67 | 40 | Herbert d. (7)Alex De Minaur [AUS] | 7-5 2-6 7-6(8) | (ch) | 0.83 | 7.8% | 5.2% | 61.2% | 71.8% | 48.9% | 3/6 | 2:34 |
| 13‑Feb‑2017 | Rotterdam | Hard | SF | 109 | 11 | (3)David Goffin [BEL] d. (Q)Herbert | 6-1 6-3 | | 0.66 | 8.8% | 4.4% | 61.8% | 59.5% | 38.5% | 6/10 | 1:14 |
| 23‑Aug‑2015 | Winston-Salem | Hard | SF | 140 | 49 | (Q)Herbert d. (13)Steve Johnson [USA] | 3-6 7-6(5) 6-2 | | 0.94 | 20.9% | 3.3% | 56.0% | 76.5% | 60.0% | 4/6 | |
