| 1‑Jul‑2024 | Wimbledon | Grass | R64 | 63 | 9 | (9)Alex De Minaur [AUS] d. Munar | 6-2 6-2 7-5 | | 0.67 | 3.4% | 10.2% | 46.6% | 63.4% | 31.9% | 9/17 | 2:05 |
| 27‑May‑2024 | Roland Garros | Clay | R64 | 64 | 11 | (11)Alex De Minaur [AUS] d. Munar | 7-5 6-1 6-4 | | 0.68 | 1.0% | 12.1% | 60.6% | 56.7% | 46.2% | 6/13 | |
| 3‑May‑2021 | Madrid Masters | Clay | R64 | 87 | 24 | Alex De Minaur [AUS] d. (WC)Munar | 4-6 7-5 6-1 | | 0.84 | 2.1% | 4.2% | 78.9% | 66.7% | 35.0% | 9/13 | 2:22 |
| 5‑Nov‑2018 | NextGen Finals | Hard | SF | 76 | 31 | (2)Alex De Minaur [AUS] d. (7)Munar | 3-4(5) 4-1 4-1 3-4(4) 4-2 | | 0.73 | 2.1% | 0.0% | 63.8% | 71.7% | 44.1% | 13/17 | 2:00 |
| 31‑Jul‑2017 | Segovia CH | Hard | F | 301 | 217 | Munar d. Alex De Minaur [AUS] | 6-3 6-4 | | 1.41 | 5.3% | 0.0% | 73.7% | 73.8% | 60.0% | 1/2 | 1:10 |
| 16‑May‑2016 | Spain F14 | Clay | F | 459 | 764 | (4)Munar d. Alex De Minaur [AUS] | 7-6(5) 7-5 | | | | | | | | | |
