| 13‑Jan‑2025 | Australian Open | Hard | QF | 3 | 7 | (7)Novak Djokovic [SRB] d. (3)Alcaraz | 4-6 6-4 6-3 6-4 | (ch) | 0.94 | 8.0% | 4.0% | 73.6% | 67.4% | 33.3% | 7/13 | 3:37 |
| 29‑Jul‑2024 | Paris Olympics | Clay | F | 3 | 2 | (1)Novak Djokovic [SRB] d. (2)Alcaraz | 7-6(3) 7-6(2) | (ch) | 0.81 | 1.0% | 1.0% | 66.3% | 72.3% | 48.5% | 6/6 | |
| 1‑Jul‑2024 | Wimbledon | Grass | F | 3 | 2 | (3)Alcaraz d. (2)Novak Djokovic [SRB] | 6-2 6-2 7-6(4) | (ch) | 1.41 | 5.3% | 6.3% | 58.9% | 83.9% | 51.3% | 2/3 | 2:27 |
| 13‑Nov‑2023 | Tour Finals | Hard | SF | 2 | 1 | (1)Novak Djokovic [SRB] d. (2)Alcaraz | 6-3 6-2 | (ch) | 0.64 | 17.9% | 1.8% | 83.9% | 61.7% | 33.3% | 5/8 | 1:28 |
| 14‑Aug‑2023 | Cincinnati Masters | Hard | F | 1 | 2 | (2)Novak Djokovic [SRB] d. (1)Alcaraz | 5-7 7-6(7) 7-6(4) | (ch) | 0.93 | 8.3% | 3.8% | 63.9% | 71.8% | 47.9% | 13/16 | 3:49 |
| 3‑Jul‑2023 | Wimbledon | Grass | F | 1 | 2 | (1)Alcaraz d. (2)Novak Djokovic [SRB] | 1-6 7-6(6) 6-1 3-6 6-4 | (ch) | 1.08 | 6.0% | 4.7% | 62.7% | 70.2% | 50.0% | 10/15 | 4:43 |
| 29‑May‑2023 | Roland Garros | Clay | SF | 1 | 3 | (3)Novak Djokovic [SRB] d. (1)Alcaraz | 6-3 5-7 6-1 6-1 | (ch) | 0.77 | 2.9% | 1.9% | 71.8% | 54.1% | 48.3% | 5/12 | 3:24 |
| 2‑May‑2022 | Madrid Masters | Clay | SF | 9 | 1 | (7)Alcaraz d. (1)Novak Djokovic [SRB] | 6-7(5) 7-5 7-6(5) | (ch) | 1.01 | 2.9% | 2.9% | 66.9% | 73.6% | 51.1% | 5/6 | 3:35 |
